Method 1 :
Step1: Click '‘OK' when the following window pop-up .

Step2: Click on the check box 'Do not ask me again', and then click 'No'.

Method 2 : Screen it by the way of config.xml
Step 1: Exit Xskype
Step 2: Open 'My Computer' -> Tools -> Folder Options, as Figure 1

Figure 1
Step 3: Folder Options -> View -> Show hidden files and folders, and then click 'ok', as Figure 2

Figure 2
Step 4: Please find Skype ID file on system disk, and amend the content of 'config.xml'.
For example, a person installed the system on D disk, the system users is XSkypeUser11, SkypeID is Yeastar.xskype11
Open D disk, find the config. file of skype user yeastar.xskype11, open it with Notepad, as Figure 3

Figure 3
Find <General> on config file, and add codes(<AddToContactsWizardDisabled>1</AddToContactsWizardDisabled>) behind <General> , as Figure 4

Save the Change
Step 5: Modify Config.xml files of other Skype ID, follow the steps as same as Step 4.
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